Issue 13, 1973

Osmium nitrido-complexes with triphenyl-phosphine, -arsine, and -stibine, with evidence for nitrene-like behaviour of the phosphine complex

Abstract

The new complexes [OsNX3(AsPh3)2] and [OsNCl3(LPh3)2](X = Cl or Br, L = P or Sb) have been made; we propose that nucleophilic attack of the nitrogen atom by triphenylphosphine occurs in some of these complexes to give derivatives of triphenylphosphine imine.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 418-419

Osmium nitrido-complexes with triphenyl-phosphine, -arsine, and -stibine, with evidence for nitrene-like behaviour of the phosphine complex

W. P. Griffith and D. Pawson, J. Chem. Soc., Chem. Commun., 1973, 418 DOI: 10.1039/C39730000418

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