A new type of σ-bonded organosilver compound: [Ag–C(OR)= NAr]3
Abstract
Reaction of alcoholic KOH with (ArNC)AgCI gives σ-bonded organosilver compounds [Ag–C(OR)= NAr]3, which undergo metathesis with chloro-complexes of AuI, HgII, and PtII to give σ-bonded alkyl complexes of these metals.