Issue 7, 1973

A new type of σ-bonded organosilver compound: [Ag–C(OR)= NAr]3

Abstract

Reaction of alcoholic KOH with (ArNC)AgCI gives σ-bonded organosilver compounds [Ag–C(OR)= NAr]3, which undergo metathesis with chloro-complexes of AuI, HgII, and PtII to give σ-bonded alkyl complexes of these metals.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 260-260

A new type of σ-bonded organosilver compound: [Ag–C(OR)= NAr]3

G. Minghetti, F. Bonati and M. Massobrio, J. Chem. Soc., Chem. Commun., 1973, 260 DOI: 10.1039/C39730000260

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