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6-Hydroxyphenazine-1-carboxylic acid was shown to be an efficient precursor for iodinin in Brevibacterium iodinum, the hydroxy-group in the precursor being present before formation of the phenazine ring system; the result has important implications in respect of the biosynthesis of this ring system.
R. B. Herbert, F. G. Holliman and P. N. Ibberson, J. Chem. Soc., Chem. Commun., 1972, 355 DOI: 10.1039/C39720000355
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