The carbonyl–diphosphine bridged dimer [(π-C5H5)Fe(CO)]2[Ph2P(CH2)3PPh2]{Fe2(diphos)} is reversibly oxidized electrochemically to the cation Fe2(diphos)+ which disproportionates in acetonitrile and is further oxidized to the transient dication Fe2(diphos)2+.
J. A. Ferguson and T. J. Meyer, J. Chem. Soc. D, 1971, 1544 DOI: 10.1039/C29710001544
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