The structures of a delocalised pseudo-π-allylic (three electron)π-oxopropyl manganese tricarbonyl complex (A) and a σ-bonded Mn–C oxobutyl tricarbonyl complex (B) have been determined by three-dimensional X-ray structural analysis.
M. A. Bennett, G. B. Robertson, R. Watt and P. O. Whimp, J. Chem. Soc. D, 1971, 752 DOI: 10.1039/C29710000752
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