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Comparative incorporation experiments with [1′-14C]orsellinic acid (1) and [1′-14C]-2,4-dihydroxy-5,6-dimethylbenzoic acid (2) suggest that only the latter is a specific precursor of mycophenolic acid; the implication of this result in terms of the biosynthetic sequence is discussed, and preliminary studies on the mode of construction of the terpenoid side-chain are also reported.
C. T. Bedford, J. C. Fairlie, P. Knittel, T. Money and G. T. Phillips, J. Chem. Soc. D, 1971, 323 DOI: 10.1039/C29710000323
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