Effect of 4-t-butyl and other 4-substituents on the rate constants for nucleophilic displacement with thiophenate anion in diethylene glycol at the benzyl methylene groups in 1-benzylpiperidine benzobromides
Abstract
A 4-t-butyl group approximately doubles the overall rate constants for nucleophillic displacement with thiophenate anion at the benzyl methylene groups in 1-benzylpiperidine benzobromides.