SCHEDULED MAINTENANCE
The 3α-cholestanyl ester of 5-(4-benzoylphenyl)-valeric acid underwent direct photochemical hydrogen transfer upon irradiation, thereby providing a simple route to Δ14 and Δ16 steroids, in 53% yield: a minor proportion of this reaction led to steroidal macrolides.
J. E. Baldwin, A. K. Bhatnagar and R. W. Harper, J. Chem. Soc. D, 1970, 659 DOI: 10.1039/C29700000659
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