Issue 6, 2005
From the journal:

Analyst

Significant viscosity dependent deviations from classical van Deemter theory in liquid chromatography with porous silica monolithic columns

Pavel N. Nesterenko,*a   Marina A. Rybalkoa  and  Brett Paullb  

* Corresponding authors

a Department of Chemstry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
E-mail: PavelN@analyt.chem..msu.ru
Fax: 007 (095) 9394675
Tel: 007 (095) 9394416

b National Centre for Sensor Research, School of Chemical Sciences, Dublin City University, Glasnevin, Dublin 9, Ireland
E-mail: Brett.Paull@dcu.ie
Fax: +353 1(0) 7005503
Tel: +353 1(0) 7005060

Abstract

Significant deviations from classical van Deemter behaviour, indicative of turbulent flow liquid chromatography, has been recorded for mobile phases of varying viscosity on porous silica monolithic columns at elevated mobile phase flow rates.

Graphical abstract: Significant viscosity dependent deviations from classical van Deemter theory in liquid chromatography with porous silica monolithic columns

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Article information

DOI
https://doi.org/10.1039/B502514A
Article type
Communication
Submitted
17 Feb 2005
Accepted
07 Apr 2005
First published
15 Apr 2005

Analyst, 2005,130, 828-830

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Significant viscosity dependent deviations from classical van Deemter theory in liquid chromatography with porous silica monolithic columns

P. N. Nesterenko, M. A. Rybalko and B. Paull, Analyst, 2005, 130, 828 DOI: 10.1039/B502514A

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