Electron field emission of water-based inkjet printed graphene films

Abstract

Solution-processed graphene is extremely attractive for the realization of large area and patterned graphene films for field emitting devices. Previous studies have focussed only on the use of reduced graphene oxide; however, solution-processed graphene can also be produced by other approaches, giving rise to nanosheets with different surface chemistries and lateral and thickness distributions. Here, we report the field emission characterization of films made of water-based graphene ink, prepared by liquid phase exfoliation, and inkjet printed with an area of 2.5 mm² on silicon (Si/SiO₂) substrates. These films show excellent field emission properties, comparable to those measured on single flakes and carbon nanotubes with the same setup, and they show a remarkably high maximum current density (up to ∼723 A cm⁻²), making them very attractive for field emission devices.