Solar-driven plasmon-enhanced photocatalysis: Co2+-doped ZnFe2O4 nanospheres-embedded ZnO nanosheets for effective degradation of dyes and antibiotics

Abstract

To ensure sustainable management and the availability of water and sanitation for all, a UN sustainable development goal (SDG) focused on promising methods to eliminate aqueous pollutants is urgently required. In this regard, solar photocatalysis, driven by freely available sunlight using low-cost, reusable photocatalysts, is a promising approach. In this context, we present a novel full-solar-spectrum photocatalyst with promising efficiency attributed to its laddered heterojunction and Ag-based plasmon enhanced activity. Specifically, it comprised Co²⁺-doped zinc-ferrite nanoparticles embedded on zinc oxide sheets that were later conformally coated with a small weight fraction (2.5%) of Ag under sunlight. The photocatalyst was optimized for different synthesis methods, post-synthesis temperatures, and different compositions with orange G as a model pollutant. Unlike previous reports, without any scavengers, the photocatalyst was effective for highly polluted water with a chemical oxygen demand (COD) of ∼740 ppm, eliminating 66% of it within an hour. We have coined a new term, solar photo-oxidation efficiency (SPOE), to describe the photocatalyst's performance. SPOE was directly dependent on the pollutant concentration and was found to be 72% for 400 ppm ciprofloxacin, with an apparent quantum yield of 36%. The promising activity of our photocatalyst continued even after several reuses. The generation of hydroxyl and superoxide radicals was confirmed by respective confirmatory tests. Scavenging tests indicated the highest contribution of superoxide radicals and holes in photodegradation. Our photocatalyst is promising and holds enormous potential for use in the treatment of diverse pollutants.