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Chemical Communications

Highly emissive boron-α-thioimidinates: substituent control of photophysics and charge transport properties

Anna Chandrasekar Murali,a   Ankit Raj,b   Sabari Veerapathiran,a   Satyaprasad P. Senanayak, ORCID logo *b   Krishnan Venkatasubbaiah ORCID logo *c  and  Vadapalli Chandrasekhar ORCID logo *a  

* Corresponding authors

a Tata Institute of Fundamental Research, Hyderabad, India
E-mail: vc@tifrh.res.in

b Nanoelectronics and Device Physics Lab, School of Physical Science, National Institute of Science Education and Research, An OCC of Homi Bhabha National Institute, Bhubaneswar, Odisha, India
E-mail: satyaprasad@niser.ac.in

c Department of Chemical Sciences, National Institute of Science Education and Research, An OCC of Homi Bhabha National Institute, Bhubaneswar, Odisha, India
E-mail: krishv@niser.ac.in

Abstract

We report the first family of boron-α-thioimidinates, (C6F5)2B(N^S). Our findings demonstrate that this group of compounds have significant photophysical properties (ΦF = 0.6% to 93.0%). These boron-based molecules also display bulk electron mobility (10−5 cm2 V−1 s−1).

Graphical abstract: Highly emissive boron-α-thioimidinates: substituent control of photophysics and charge transport properties

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Article information

DOI
https://doi.org/10.1039/D5CC05332C
Article type
Communication
Submitted
16 Sep 2025
Accepted
15 Oct 2025
First published
17 Oct 2025

Chem. Commun., 2025, Advance Article

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Highly emissive boron-α-thioimidinates: substituent control of photophysics and charge transport properties

A. C. Murali, A. Raj, S. Veerapathiran, S. P. Senanayak, K. Venkatasubbaiah and V. Chandrasekhar, Chem. Commun., 2025, Advance Article , DOI: 10.1039/D5CC05332C

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