Issue 20, 2024, Issue in Progress

Elucidating the performance of hexamethylene tetra-amine interlinked bimetallic NiCo-MOF for efficient electrochemical hydrogen and oxygen evolution

Abstract

Bimetallic metal–organic frameworks (MOFs) play a significant role in the electrocatalysis of water due to their large surface area and availability of increased numbers of pores. For the inaugural time, we examine the effectiveness of a hexamethylene tetra-amine (HMT)-induced 3D NiCo-MOF-based nanostructure as a potent bifunctional electrocatalyst with superior performance for overall water splitting in alkaline environments. The structural, morphological, and electrochemical properties of the as-synthesized bifunctional catalyst were examined thoroughly before analyzing its behavior towards electrochemical water splitting. The HMT-based NiCo-MOF demonstrated small overpotential values of 274 mV and 330 mV in reaching a maximum current density of 30 mA cm−2 for hydrogen and oxygen evolution mechanisms, respectively. The Tafel parameter also showed favorable HER/OER reaction kinetics, with slopes of 78 mV dec−1 and 86 mV dec−1 determined during the electrochemical evaluation. Remarkably, the NiCo-HMT electrode exhibited a double-layer capacitance of 4 mF cm−2 for hydrogen evolution and 23 mF cm−2 for oxygen evolution, while maintaining remarkable stability even after continuous operation for 20 hours. This research offers a valuable blueprint for implementing a cost-effective and durable MOF-based bifunctional catalytic system that has proven to be effective for complete water splitting. Decomposition of water under higher current densities is crucial for effective long-term generation and commercial consumption of hydrogen.

Graphical abstract: Elucidating the performance of hexamethylene tetra-amine interlinked bimetallic NiCo-MOF for efficient electrochemical hydrogen and oxygen evolution

Article information

Article type
Paper
Submitted
13 Jan 2024
Accepted
05 Apr 2024
First published
26 Apr 2024
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2024,14, 13837-13849

Elucidating the performance of hexamethylene tetra-amine interlinked bimetallic NiCo-MOF for efficient electrochemical hydrogen and oxygen evolution

R. Zahid, M. R. Abdul Karim, F. S. Khan and M. A. Marwat, RSC Adv., 2024, 14, 13837 DOI: 10.1039/D4RA00340C

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