Solvating lithium and tethering aluminium using di-coordination-strength anions for low-temperature lithium metal batteries

Abstract

Lithium bis(fluorosulfonyl)imide (LiFSI) corrodes aluminium (Al) current collector, but this corrosion can be impeded using di-coordination-strength anions. This concept adopts the weakly coordinated anion (FSI⁻) to exert high ionic transport kinetics, and the strongly coordinated anion (nitride, NO₃⁻) to stabilize the Al foil surface. Such simultaneous Li solvation and Al tethering, highlight the importance of solvation chemistry to mediating Li transport and Al corrosion.