Replacement of the heteroatom from Si to Ge has a strong influence on the luminescent properties of a series of hybrid, sandwich-type K5[Ln(α-GeW11O39)(C20H22Br2N2O4)]·14H2O (1Ge-Ln, Ln = Sm to Lu) anions. Interestingly, the Gd and Yb derivatives retain their ability to display slow relaxation of magnetisation.
J. Bustamante-Fernández, E. Ruiz-Bilbao, C. Rodríguez-Esteban, M. Gonidec, J. A. Garcia, L. Lezama, J. M. Gutierrez-Zorrilla, I. Oyarzabal and B. Artetxe, Dalton Trans., 2024, Accepted Manuscript , DOI: 10.1039/D4DT01379D
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