Issue 22, 2024

Carbon encapsulated nanoparticles: materials science and energy applications

Abstract

The technological implementation of electrochemical energy conversion and storage necessitates the acquisition of high-performance electrocatalysts and electrodes. Carbon encapsulated nanoparticles have emerged as an exciting option owing to their unique advantages that strike a high-level activity–stability balance. Ever-growing attention to this unique type of material is partly attributed to the straightforward rationale of carbonizing ubiquitous organic species under energetic conditions. In addition, on-demand precursors pave the way for not only introducing dopants and surface functional groups into the carbon shell but also generating diverse metal-based nanoparticle cores. By controlling the synthetic parameters, both the carbon shell and the metallic core are facilely engineered in terms of structure, composition, and dimensions. Apart from multiple easy-to-understand superiorities, such as improved agglomeration, corrosion, oxidation, and pulverization resistance and charge conduction, afforded by the carbon encapsulation, potential core–shell synergistic interactions lead to the fine-tuning of the electronic structures of both components. These features collectively contribute to the emerging energy applications of these nanostructures as novel electrocatalysts and electrodes. Thus, a systematic and comprehensive review is urgently needed to summarize recent advancements and stimulate further efforts in this rapidly evolving research field.

Graphical abstract: Carbon encapsulated nanoparticles: materials science and energy applications

Article information

Article type
Review Article
Submitted
16 May 2024
First published
24 Sep 2024

Chem. Soc. Rev., 2024,53, 11100-11164

Carbon encapsulated nanoparticles: materials science and energy applications

K. Guo, L. Bao, Z. Yu and X. Lu, Chem. Soc. Rev., 2024, 53, 11100 DOI: 10.1039/D3CS01122D

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