Herein, we presented an enantioselective intramolecular Diels-Alder (IMDA) reaction with vinyl branched vinylidene ortho-quinone methide (VQM). The control of site selectivity in the IMDA reaction led to both chiral bridged bicyclo[4.3.1] and [5.3.1] architectures with high isolated yields (up to 85%) and excellent enantioselectivities (up to 97% ee).
K. Li, Z. Zhao, W. Qin, Y. Liu and H. Yan, Chem. Commun., 2024, Accepted Manuscript , DOI: 10.1039/D4CC02850C
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