Electronic interaction between dimethyl carbonate and Li+ studied by attenuated total reflectance far-ultraviolet spectroscopy

Hitomi Sato; Nami Ueno; Ichiro Tanabe

doi:10.1039/D4CC01775G

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Electronic interaction between dimethyl carbonate and Li⁺ studied by attenuated total reflectance far-ultraviolet spectroscopy†

Hitomi Sato,^a Nami Ueno*^a and Ichiro Tanabe

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, College of Science, Rikkyo University, 3-34-1, Nishi-Ikebukuro, Toshima-ku, Tokyo 171-8501, Japan
E-mail: itanabe@rikkyo.ac.jp

Abstract

Organic electrolytes with Li⁺ were analyzed by far-ultraviolet (≤200 nm) spectroscopy, achieved by an attenuated total reflectance setup. The spectra showed a redshift with Li⁺ addition, attributed to the charge transfer, as revealed by quantum chemical calculations. Multivariate analysis successfully decomposed the spectra into pure solvent and Li-coordinated solvent components.

Download options Please wait...

Supplementary files

Supplementary information PDF (1754K)

Article information

DOI: https://doi.org/10.1039/D4CC01775G
Article type: Communication
Submitted: 15 Apr 2024
Accepted: 21 May 2024
First published: 21 May 2024

Download Citation

Chem. Commun., 2024, Advance Article

Permissions

Request permissions

Electronic interaction between dimethyl carbonate and Li⁺ studied by attenuated total reflectance far-ultraviolet spectroscopy

H. Sato, N. Ueno and I. Tanabe, Chem. Commun., 2024, Advance Article , DOI: 10.1039/D4CC01775G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Chemical Communications