Triptycene-based diiron(II) mesocates: spin-crossover in solution

Riccardo Mobili; Giovanni Preda; Daniele Dondi; Enrico Monzani; Dhanalakshmi Vadivel; Chiara Massera; Dario Pasini; Valeria Amendola

doi:10.1039/D4CC00812J

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Triptycene-based diiron(ii) mesocates: spin-crossover in solution†

Riccardo Mobili,

*^ab Giovanni Preda,

^a Daniele Dondi,

^a Enrico Monzani,

^a Dhanalakshmi Vadivel,

^a Chiara Massera,

^c Dario Pasini

^a and Valeria Amendola

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Pavia, viale Torquato Taramelli 12, 27100 Pavia, Italy
E-mail: valeria.amendola@unipv

^b Sorbonne Université, CNRS, Institut Parisien de Chimie Moléculaire, 4 Place Jussieu, Paris, France
E-mail: riccardo.mobili@sorbonne-universite.fr

^c Department of Chemistry, Life Science and Environmental Sustainability University of Parma, Parco Area delle Scienze 17/A, Parma, Italy

Abstract

Triptycene-based diiron(II) and dizinc(II) mesocates were obtained using a novel rigid ligand with two pyridylbenzimidazole chelating units fused into the triptycene scaffold. Studies on the diiron(II) assembly in solution showed that the complex undergoes thermal-induced one-step spin-crossover with T_1/2 at 243 K (Evans method).

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DOI: https://doi.org/10.1039/D4CC00812J
Article type: Communication
Submitted: 19 Feb 2024
Accepted: 26 Apr 2024
First published: 29 Apr 2024
This article is Open Access

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Chem. Commun., 2024, Advance Article

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Triptycene-based diiron(II) mesocates: spin-crossover in solution

R. Mobili, G. Preda, D. Dondi, E. Monzani, D. Vadivel, C. Massera, D. Pasini and V. Amendola, Chem. Commun., 2024, Advance Article , DOI: 10.1039/D4CC00812J

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Chemical Communications

Triptycene-based diiron(ii) mesocates: spin-crossover in solution†

Abstract

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Triptycene-based diiron(II) mesocates: spin-crossover in solution

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