Electrospinning-assisted porous skeleton electrolytes for semi-solid Li–O2 batteries

Abstract

Solid-state lithium–oxygen batteries offer great promise in meeting the practical demand for high-energy-density and safe energy storage. We have developed fibrous gel polymer electrolytes (GPEs) using a polyacrylonitrile (PAN) matrix via electrospinning. The 3D structure of GPEs enhances electrolyte absorption, while the interconnected design promotes strong interactions between Li⁺ and polar groups within the PAN matrix, thereby improving ion transport efficiency. In practical tests, both lithium symmetric cells and Li–O₂ batteries demonstrated the ability to operate at high current densities over long cycles.