New P,Nsp3 bidentate ligands containing two chiral carbon centers were developed and applied to palladium-catalyzed asymmetric allylic substitution reactions. Good generalities with various nucleophiles, including carbon, nitrogen and oxygen containing nucleophiles, were achieved with up to 96% ee and 98% yield. This reaction provides an efficient method for the asymmetric formation of C–C, C–N and C–O bonds.
Q. Su, C. Hou, D. Wei, H. Qin, D. Liang and X. Hu, Org. Biomol. Chem., 2023, 21, 4874 DOI: 10.1039/D3OB00519D
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