Issue 46, 2023
From the journal:

Dalton Transactions

Assembly of dysprosium(iii) cubanes in a metal–organic framework with an ecu topology and slow magnetic relaxation†

Dong Shao, ORCID logo *a   Yi Wan,a   Jiong Yang,c   Zhijun Ruan,a   Junlun Zhua  and  Le Shi ORCID logo *b  

* Corresponding authors

a Hubei Key Laboratory of Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University, Huanggang 438000, P. R. China
E-mail: shaodong@nju.edu.cn

b Stoddart Institute of Molecular Science, Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China

c Department of Chemistry, Southern University of Science and Technology (SUSTech), Shenzhen 518055, P. R. China

Abstract

A dysprosium(III) metal–organic framework constructed using dysprosium(III) cubanes as secondary building units has been reported to exhibit field-induced slow magnetic relaxation behavior and an unprecedented ecu topology, which is the first example of an 8-connected Ln-cubane-based framework material and a rare Dy4-MOF showing slow magnetic relaxation.

Graphical abstract: Assembly of dysprosium(iii) cubanes in a metal–organic framework with an ecu topology and slow magnetic relaxation

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Article information

DOI
https://doi.org/10.1039/D3DT03137C
Article type
Communication
Submitted
24 Sep 2023
Accepted
12 Nov 2023
First published
14 Nov 2023

Dalton Trans., 2023,52, 17114-17118

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Assembly of dysprosium(III) cubanes in a metal–organic framework with an ecu topology and slow magnetic relaxation

D. Shao, Y. Wan, J. Yang, Z. Ruan, J. Zhu and L. Shi, Dalton Trans., 2023, 52, 17114 DOI: 10.1039/D3DT03137C

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