Issue 2, 2024

Phenylsilver – an unexpected one-dimensional coordination polymer of silver(i) tetrads

Abstract

Herein we present the structures of two distinct one-dimensional coordination polymers of phenylsilver. Both polymers consist of phenylsilver tetrads inter-connected via short silver–silver contacts (either one or two). The underlying mechanism for the formation by transmetalation was validated by synthesising an analogous fluorinated derivative of phenylsilver.

Graphical abstract: Phenylsilver – an unexpected one-dimensional coordination polymer of silver(i) tetrads

Supplementary files

Article information

Article type
Communication
Submitted
14 Sep 2023
Accepted
21 Nov 2023
First published
29 Nov 2023

Dalton Trans., 2024,53, 423-427

Phenylsilver – an unexpected one-dimensional coordination polymer of silver(I) tetrads

T. Lenz and M. Hebenbrock, Dalton Trans., 2024, 53, 423 DOI: 10.1039/D3DT03007E

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