Three dimensional cyclic trinuclear units based metal–covalent organic frameworks for electrochemical CO2RR

Zhenli Liu; Shichen Yan; Qianrong Fang; Yaobing Wang; Daqiang Yuan

doi:10.1039/D3CC02285D

Three dimensional cyclic trinuclear units based metal–covalent organic frameworks for electrochemical CO₂RR†

Zhenli Liu,

^ab Shichen Yan,

*^a Qianrong Fang,

^c Yaobing Wang

^a and Daqiang Yuan

*^a

Author affiliations

* Corresponding authors

^a CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, Fujian, P. R. China
E-mail: yansch@fjirsm.ac.cn, ydq@fjirsm.ac.cn

^b College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, P. R. China

^c State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China

Abstract

A three-dimensional metal–covalent organic framework (3D-MCOF) based on cyclic trinuclear units was synthesized using organic tetrahedral linkers and copper-based cyclic trinuclear complexes. The novel type of 3D-MCOF, named 3D-CTU-MCOF, with the ctn topology, is reported herein for the first time. Our study demonstrated enhanced electrocatalytic capacity for CO₂ reduction reaction of 3D-CTU-MCOF compared to independent cyclic trinuclear units.

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Article information

DOI: https://doi.org/10.1039/D3CC02285D
Article type: Communication
Submitted: 11 May 2023
Accepted: 12 Jul 2023
First published: 13 Jul 2023
This article is Open Access

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Chem. Commun., 2023,59, 9615-9617

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Three dimensional cyclic trinuclear units based metal–covalent organic frameworks for electrochemical CO₂RR

Z. Liu, S. Yan, Q. Fang, Y. Wang and D. Yuan, Chem. Commun., 2023, 59, 9615 DOI: 10.1039/D3CC02285D

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Chemical Communications

Three dimensional cyclic trinuclear units based metal–covalent organic frameworks for electrochemical CO₂RR†

Abstract

Supplementary files

Article information

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Three dimensional cyclic trinuclear units based metal–covalent organic frameworks for electrochemical CO₂RR

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