A hexagon based Mn(II) rod metal–organic framework – structure, SF6 gas sorption, magnetism and electrochemistry

Francoise M. Amombo Noa; Ocean Cheung; Michelle Åhlén; Elisabet Ahlberg; Priyanka Nehla; Germán Salazar-Alvarez; Soheil Ershadrad; Biplab Sanyal; Lars Öhrström

doi:10.1039/D2CC06916D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A hexagon based Mn(ii) rod metal–organic framework – structure, SF₆ gas sorption, magnetism and electrochemistry†

Francoise M. Amombo Noa,

*^a Ocean Cheung,

^b Michelle Åhlén,^b Elisabet Ahlberg,

^c Priyanka Nehla,^b Germán Salazar-Alvarez,

^b Soheil Ershadrad,^d Biplab Sanyal

^d and Lars Öhrström

*^a

Author affiliations

* Corresponding authors

^a Chemistry and Biochemistry, Department of Chemistry and Chemical Engineering, Chalmers University of Technology, Gothenburg SE-41296, Sweden
E-mail: mystere@chalmers.se, ohrstrom@chalmers.se

^b Department of Materials Science and Engineering, Ångström Laboratory, Uppsala University, Uppsala SE-751 03, Sweden

^c Department of Chemistry & Molecular Biology, University of Gothenburg, Gothenburg 405 30, Sweden

^d Department of Physics & Astronomy, Uppsala University, Box-516, Uppsala 75120, Sweden

Abstract

A manganese(II) metal–organic framework based on the hexatopic hexakis(4-carboxyphenyl)benzene, cpb⁶⁻: [Mn₃(cpb)(dmf)₃], was solvothermally prepared showing a Langmuir area of 438 m² g⁻¹, rapid uptake OF sulfur hexafluoride (SF₆) as well as electrochemical and magnetic properties, while single crystal diffraction reveals an unusual rod-MOF topology.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D2CC06916D
Article type: Communication
Submitted: 19 Dec 2022
Accepted: 25 Jan 2023
First published: 25 Jan 2023
This article is Open Access

Download Citation

Chem. Commun., 2023,59, 2106-2109

Permissions

Request permissions

A hexagon based Mn(II) rod metal–organic framework – structure, SF₆ gas sorption, magnetism and electrochemistry

F. M. Amombo Noa, O. Cheung, M. Åhlén, E. Ahlberg, P. Nehla, G. Salazar-Alvarez, S. Ershadrad, B. Sanyal and L. Öhrström, Chem. Commun., 2023, 59, 2106 DOI: 10.1039/D2CC06916D

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications