Issue 21, 2023
From the journal:

Chemical Communications

Adsorptive removal of iodate oxyanions from water using a Zr-based metal–organic framework†

Christopher Copeman,a   Hudson A. Bicalho,a   Maxwell W. Terban, ORCID logo b   Diego Troya, ORCID logo c   Martin Etter,d   Paul L. Frattini,e   Daniel M. Wellse  and  Ashlee J. Howarth ORCID logo *a  

* Corresponding authors

a Department of Chemistry and Biochemistry, and Centre for NanoScience Research, Concordia University, 7141 Sherbrooke St W., Montreal, QC, Canada
E-mail: ashlee.howarth@concordia.ca

b Max Planck Institute for Solid State Research, Heisenbergstraße 1, Stuttgart 70569, Germany

c Department of Chemistry, Virginia Tech, Blacksburg, Virginia 24061, USA

d Deutsches Elektronen-Synchrotron DESY, Notkestraße 85, Hamburg, Germany

e Electric Power Research Institute Inc., 3420 Hillview Ave, Palo Alto, CA 94304, USA

Abstract

A Zr6-based metal–organic framework (MOF), MOF-808, is investigated for the adsorptive removal of IO3− from aqueous solutions, due to its high surface area and abundance of open metal sites. The uptake kinetics, adsorption capacity and binding mode are studied, showing a maximum uptake capacity of 233 mg g−1, the highest reported by any material.

Graphical abstract: Adsorptive removal of iodate oxyanions from water using a Zr-based metal–organic framework

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Article information

DOI
https://doi.org/10.1039/D2CC06558D
Article type
Communication
Submitted
01 Dec 2022
Accepted
01 Feb 2023
First published
01 Feb 2023

Chem. Commun., 2023,59, 3071-3074

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Adsorptive removal of iodate oxyanions from water using a Zr-based metal–organic framework

C. Copeman, H. A. Bicalho, M. W. Terban, D. Troya, M. Etter, P. L. Frattini, D. M. Wells and A. J. Howarth, Chem. Commun., 2023, 59, 3071 DOI: 10.1039/D2CC06558D

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