Issue 2, 2022

An investigation of palladium-catalyzed Stille-type cross-coupling of nitroarenes in perylenediimide series

Abstract

We report herein an unprecedented palladium-catalyzed cross-coupling reaction between mononitro-perylenediimide (PDI) and various arylstannanes. Optimized conditions developed with this Stille-type reaction allow the grafting of (hetero)aryls of various electronic nature in the bay region of PDIs. Moreover, we capitalized on the high selectivity of this cross-coupling through the desymmetrization of the dinitro-PDI substrate.

Graphical abstract: An investigation of palladium-catalyzed Stille-type cross-coupling of nitroarenes in perylenediimide series

Supplementary files

Article information

Article type
Communication
Submitted
22 Nov 2021
Accepted
09 Dec 2021
First published
11 Dec 2021

Org. Biomol. Chem., 2022,20, 362-365

An investigation of palladium-catalyzed Stille-type cross-coupling of nitroarenes in perylenediimide series

A. Makhloutah, D. Hatych, T. Chartier, L. Rocard, A. Goujon, F. Felpin and P. Hudhomme, Org. Biomol. Chem., 2022, 20, 362 DOI: 10.1039/D1OB02291A

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