Issue 29, 2022
From the journal:

New Journal of Chemistry

Enhancement of association constants of various charge-transfer complexes in siloxane solvents†

Shogo Amemori, ORCID logo *abc   Ryosuke Hamamotod  and  Motohiro Mizuno ORCID logo *abc  

* Corresponding authors

a NanoMaterials Research Institute, Kanazawa University, Kanazawa 920-1192, Japan
E-mail: amemori@staff.kanazawa-u.ac.jp, mizuno@se.kanazawa-u.ac.jp

b Graduate School of Natural Science and Technology, Kanazawa University, Kanazawa 920-1192, Japan

c Institute for Frontier Science Initiative, Kanazawa University, Kanazawa 920-1192, Japan

d School of Chemistry, College of Science and Engineering, Kanazawa University, Kanazawa 920-1192, Japan

Abstract

The association constants of various charge-transfer complexes were evaluated in n-hexane, octamethyltrisiloxane and PDMS to investigate the solvent effect. Higher association constants were observed in siloxanes. The association constant in PDMS increased (1.8–5.7 times) with increasing aromatic core size, implying the significant influence of aromatic cores on the solvent effect.

Graphical abstract: Enhancement of association constants of various charge-transfer complexes in siloxane solvents

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Article information

DOI
https://doi.org/10.1039/D2NJ00214K
Article type
Communication
Submitted
14 Jan 2022
Accepted
26 May 2022
First published
24 Jun 2022
This article is Open Access
Creative Commons BY-NC license

New J. Chem., 2022,46, 13856-13860

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Enhancement of association constants of various charge-transfer complexes in siloxane solvents

S. Amemori, R. Hamamoto and M. Mizuno, New J. Chem., 2022, 46, 13856 DOI: 10.1039/D2NJ00214K

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