An isoindoline bridged [M(η6-arene)2]+ (M = Re, 99mTc) ansa-arenophane and its dinuclear macrocycles with axial chirality

Joshua Csucker; Da Kyung Jo; Qaisar Nadeem; Olivier Blacque; Thomas Fox; Henrik Braband; Roger Alberto

doi:10.1039/D2DT00743F

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An isoindoline bridged [M(η⁶-arene)₂]⁺ (M = Re, ^99mTc) ansa-arenophane and its dinuclear macrocycles with axial chirality†

Joshua Csucker,

^a Da Kyung Jo,^a Qaisar Nadeem,^a Olivier Blacque,

^a Thomas Fox,^a Henrik Braband

^a and Roger Alberto

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Zurich, Winterthurerstrasse 190, CH-8057 Zurich, Switzerland
E-mail: ariel@chem.uzh.ch

Abstract

This work presents a straightforward method for the preparation of an isoindoline bridged [M(arene)₂]⁺ (M = Re, ^99mTc) ansa-[3]arenophane. This intramolecular formation of an ansa-complex is accompanied by the intermolecular formation of a pair of isoindoline bridged macrocyclic dinuclear sandwich complexes, one of which exhibits axial chirality.

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Article information

DOI: https://doi.org/10.1039/D2DT00743F
Article type: Communication
Submitted: 09 Mar 2022
Accepted: 31 May 2022
First published: 01 Jun 2022
This article is Open Access

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Dalton Trans., 2022,51, 9591-9595

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An isoindoline bridged [M(η⁶-arene)₂]⁺ (M = Re, ^99mTc) ansa-arenophane and its dinuclear macrocycles with axial chirality

J. Csucker, D. K. Jo, Q. Nadeem, O. Blacque, T. Fox, H. Braband and R. Alberto, Dalton Trans., 2022, 51, 9591 DOI: 10.1039/D2DT00743F

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