Issue 63, 2022
From the journal:

Chemical Communications

Regulable cross-coupling of alcohols and benzothiazoles via a noble-metal-free photocatalyst under visible light†

Zi-Tong Pan,a   Xu-Kuan Qi,b   Qian Xiao,a   Xi-Wen Liang,a   Jian-Ji Zhong, ORCID logo a   Jing-Xin Jian ORCID logo *a  and  Qing-Xiao Tong ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Key Laboratory for Preparation and Application of Ordered Structural Material of Guangdong Province, and Guangdong Provincial Key Laboratory of Marine Disaster Prediction and Prevention, Shantou University, Shantou, Guangdong, China
E-mail: jxjian@stu.edu.cn, qxtong@stu.edu.cn

b State Key Lab of Urban Water Resource and Environment, School of Science, Harbin Institute of Technology (Shenzhen), Shenzhen, Guangdong, China

Abstract

Here, we realize a regulable cross-coupling reaction using alcohols as alkylating reagents to functionalize benzothiazoles. Two types of cross-coupling products are obtained with the highest isolated yields of up to 99% and 90% for alkyl- and acetyl-derived benzothiazoles, respectively, which opens up a broad research prospect for expanding alcohols as alkylating reagents.

Graphical abstract: Regulable cross-coupling of alcohols and benzothiazoles via a noble-metal-free photocatalyst under visible light

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Article information

DOI
https://doi.org/10.1039/D2CC03234A
Article type
Communication
Submitted
08 Jun 2022
Accepted
07 Jul 2022
First published
07 Jul 2022

Chem. Commun., 2022,58, 8810-8813

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Regulable cross-coupling of alcohols and benzothiazoles via a noble-metal-free photocatalyst under visible light

Z. Pan, X. Qi, Q. Xiao, X. Liang, J. Zhong, J. Jian and Q. Tong, Chem. Commun., 2022, 58, 8810 DOI: 10.1039/D2CC03234A

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