Issue 60, 2022
From the journal:

Chemical Communications

Rapid access to organic triflates based on flash generation of unstable sulfonium triflates in flow†

Masahiro Takumi, ORCID logo a   Hodaka Sakaue,a   Daiki Shibasakia  and  Aiichiro Nagaki ORCID logo ‡*a  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Kyoto, Japan

Abstract

Flash (extremely fast) electrochemical generation of unstable arylbis(arylthio)sulfonium triflates [ArS(ArSSAr)]+ [OTf]− that are unsuitable for accumulation in batch processes was achieved within 10 s in a divided-type flow electrochemcial reactor, enabling one-flow access to vinyl triflates, short-lived oxocarbenium triflates and glycosyl triflates.

Graphical abstract: Rapid access to organic triflates based on flash generation of unstable sulfonium triflates in flow

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Article information

DOI
https://doi.org/10.1039/D2CC02344J
Article type
Communication
Submitted
26 Apr 2022
Accepted
30 Jun 2022
First published
01 Jul 2022

Chem. Commun., 2022,58, 8344-8347

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Rapid access to organic triflates based on flash generation of unstable sulfonium triflates in flow

M. Takumi, H. Sakaue, D. Shibasaki and A. Nagaki, Chem. Commun., 2022, 58, 8344 DOI: 10.1039/D2CC02344J

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