Reduction of N2O with hydrosilanes catalysed by RuSNS nanoparticles

Pablo Molinillo; Bertrand Lacroix; Florencia Vattier; Nuria Rendón; Andrés Suárez; Patricia Lara

doi:10.1039/D2CC01470J

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Reduction of N₂O with hydrosilanes catalysed by RuSNS nanoparticles†

Pablo Molinillo,^a Bertrand Lacroix,

^bc Florencia Vattier,^d Nuria Rendón,

*^a Andrés Suárez

*^a and Patricia Lara

*^a

Author affiliations

* Corresponding authors

^a Instituto de Investigaciones Químicas (IIQ), Departamento de Química Inorgánica, and Centro de Innovación en Química Avanzada (ORFEO-CINQA), CSIC and Universidad de Sevilla. Avda. Américo Vespucio 49, 41092 Sevilla, Spain
E-mail: patricia@iiq.csic.es

^b Department of Material Science and Metallurgic Engineering, and Inorganic Chemistry, University of Cádiz, Spain

^c IMEYMAT: Institute of Research on Electron Microscopy and Materials of the University of Cádiz, Spain

^d Instituto de Ciencia de Materiales de Sevilla, CSIC-Universidad de Sevilla. Avda. Américo Vespucio 49, 41092 Sevilla, Spain

Abstract

A series of RuSNS nanoparticles, prepared by decomposition of Ru(COD)(COT) with H₂ in the presence of an SNS ligand, have been found to catalyse the reduction of the greenhouse gas N₂O to N₂ employing different hydrosilanes.

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Article information

DOI: https://doi.org/10.1039/D2CC01470J
Article type: Communication
Submitted: 14 Mar 2022
Accepted: 27 May 2022
First published: 30 May 2022
This article is Open Access

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Chem. Commun., 2022,58, 7176-7179

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Reduction of N₂O with hydrosilanes catalysed by RuSNS nanoparticles

P. Molinillo, B. Lacroix, F. Vattier, N. Rendón, A. Suárez and P. Lara, Chem. Commun., 2022, 58, 7176 DOI: 10.1039/D2CC01470J

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