Herein, we report for the first time single Au38 nanocluster reaction events of highly efficient electrochemiluminescence (ECL) with tri-n-propylamine radicals as a reductive co-reactant at the surface of an ultramicroelectrode (UME). The statistical analyses of individual reactions confirm stochastic single ones influenced by the applied potential.
M. Hesari, H. Ma and Z. Ding, Chem. Sci., 2021, 12, 14540 DOI: 10.1039/D1SC04018A
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