In situ constructed zeolite membranes on rough supports with the assistance of reticulated hydrotalcite interlayer

Abstract

Zeolite membranes with unique physical and chemical properties are emerging as attractive candidates for membrane separation. However, defects in the zeolite layer seriously affect their molecular sieving performance. In this study, a novel strategy for preparing compact zeolite membranes on rough supports with the assistance of a reticulated hydrotalcite layer was developed. The reticulated hydrotalcite layer was grown on the inner surface of a 170 mm length ceramic tube by an in situ hydrothermal method, and a NaA zeolite membrane was prepared on this reticulated layer by the microwave-heating method. The hydrotalcite interlayer could not only improve the smoothness and regularity of the surface of the support but also fix the Si/Al active ingredients using its reticulate structure, finally effectively improving the quality and stability of the zeolite layer. The optimal molar ratio of the synthesis solution for the synthesis of the zeolite membrane was 3Na₂O : 2SiO₂ : Al₂O₃ : 200H₂O. The permeance flux of H₂ through the zeolite membrane synthesized under the optimal conditions was high as 0.47 × 10⁻⁶ mol m⁻² s⁻¹ Pa⁻¹, and its permselectivity for H₂ over N₂ was 4.7, which was higher than the corresponding Knudsen diffusion coefficient. This study provides a new idea for the preparation of defect-free membranes on rough supports.