Issue 17, 2021
From the journal:

Dalton Transactions

Formation of an Ag→Al dative bond is avoided in reactions of an alane/tris(phosphine) ligand with monovalent silver†

Qingheng Lai,a   Nattamai Bhuvanesh,a   Jia Zhou*b  and  Oleg V. Ozerov ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Texas A&M University, College Station, TX 77842, USA
E-mail: ozerov@chem.tamu.edu

b State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, China
E-mail: jiazhou@hit.edu.cn

Abstract

An alane/tris(phospine) ligand reacts with AgOTf by coordination of three phosphines to the Ag center and transfer of triflate to the tris(pyrrolyl) Al site. Reaction with Ag[HCB11Cl11] results in the coordination of two phosphines to Ag and one to Al, with no significant Ag–Al bonding in either structure.

Graphical abstract: Formation of an Ag→Al dative bond is avoided in reactions of an alane/tris(phosphine) ligand with monovalent silver

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Article information

DOI
https://doi.org/10.1039/D1DT01068A
Article type
Communication
Submitted
30 Mar 2021
Accepted
07 Apr 2021
First published
09 Apr 2021

Dalton Trans., 2021,50, 5776-5778

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Formation of an Ag→Al dative bond is avoided in reactions of an alane/tris(phosphine) ligand with monovalent silver

Q. Lai, N. Bhuvanesh, J. Zhou and O. V. Ozerov, Dalton Trans., 2021, 50, 5776 DOI: 10.1039/D1DT01068A

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