We devised a new generation of halogen-based triplet sensitisers comprising geminal dibromides at the vinyl backbone of a BODIPY fluorophore. Incorporating geminal dibromides into the π-conjugation of BODIPY enhanced intersystem crossing due to the heavy atom effect, which in turn improved the extent of excited triplet states.
S. Dartar, M. Ucuncu, E. Karakus, Y. Hou, J. Zhao and M. Emrullahoglu, Chem. Commun., 2021, 57, 6039 DOI: 10.1039/D1CC01881G
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