Functional ligand directed assembly and electronic structure of Sn18-oxo wheel nanoclusters

Yu Zhu; Qiaohong Li; Dongsheng Li; Jian Zhang; Lei Zhang

doi:10.1039/D1CC00651G

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Functional ligand directed assembly and electronic structure of Sn₁₈-oxo wheel nanoclusters†

Yu Zhu,‡^ab Qiaohong Li,

‡^a Dongsheng Li,

^b Jian Zhang

^a and Lei Zhang

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: LZhang@fjirsm.ac.cn

^b Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, College of Materials and Chemical Engineering, China Three Gorges University, Yichang, Hubei 443002, P. R. China

Abstract

A bilayer hexagonal wheel Sn₁₈-oxo cluster, as the largest tin-oxo wheel to date, was successfully constructed by structural directing of organic ligands. Moreover, the ligands show important effects on the electronic structure and third-order nonlinear optical properties of the Sn₁₈-oxo wheel, which is demonstrated by detailed theoretical calculations.

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Article information

DOI: https://doi.org/10.1039/D1CC00651G
Article type: Communication
Submitted: 04 Feb 2021
Accepted: 16 Apr 2021
First published: 17 Apr 2021

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Chem. Commun., 2021,57, 5159-5162

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Functional ligand directed assembly and electronic structure of Sn₁₈-oxo wheel nanoclusters

Y. Zhu, Q. Li, D. Li, J. Zhang and L. Zhang, Chem. Commun., 2021, 57, 5159 DOI: 10.1039/D1CC00651G

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Chemical Communications