Issue 18, 2020
From the journal:

Green Chemistry

Improved catalytic performance of Co-MOF-74 by nanostructure construction†

Fanyu Zhang,ab   Jianling Zhang, ORCID logo *abc   Bingxing Zhang,ab   Lirong Zheng, ORCID logo d   Xiuyan Cheng,ab   Qiang Wan,ab   Buxing Han ORCID logo abc  and  Jing Zhangd  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P.R. China
E-mail: zhangjl@iccas.ac.cn

b School of Chemical Science, University of Chinese Academy of Sciences, Beijing 100049, P.R.China

c Physical Science Laboratory, Huairou National Comprehensive Science Center, Beijing 101400, P.R.China

d Beijing Synchrotron Radiation Facility (BSRF), Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, P.R.China

Abstract

Herein, we demonstrate for the first time the construction of hollow structural Co-MOF-74, whose shell is as thin as ∼50 nm and assembled by nanoparticles ranging from 8 to 18 nm. It exhibits high performance for the photocatalytic oxidation of thioanisole and thermocatalytic cyanosilylation of aldehydes.

Graphical abstract: Improved catalytic performance of Co-MOF-74 by nanostructure construction

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Supplementary files

Article information

DOI
https://doi.org/10.1039/D0GC02048F
Article type
Communication
Submitted
16 Jun 2020
Accepted
07 Aug 2020
First published
08 Aug 2020

Green Chem., 2020,22, 5995-6000

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Improved catalytic performance of Co-MOF-74 by nanostructure construction

F. Zhang, J. Zhang, B. Zhang, L. Zheng, X. Cheng, Q. Wan, B. Han and J. Zhang, Green Chem., 2020, 22, 5995 DOI: 10.1039/D0GC02048F

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