Issue 81, 2020
From the journal:

Chemical Communications

Carbonylative cycloaddition between two different alkenes enabled by reactive directing groups: expedited construction of bridged polycyclic skeletons†

Bingjian Gao,‡a   Suchen Zou,‡a   Guoqing Yang,a   Yongzheng Dinga  and  Hanmin Huang ORCID logo *abc  

* Corresponding authors

a Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, P. R. China
E-mail: hanmin@ustc.edu.cn

b Center for Excellence in Molecular Synthesis of CAS, Hefei, P. R. China

c State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, P. R. China

Abstract

A novel palladium-catalyzed highly selective hydrocarbonylative cycloaddition reaction with two different alkenes in the presence of CO enabled by a reactive directing-group is developed, which offers efficient and convenient access to lactone-containing bridged polycyclic compounds in high yield with high chemo- and stereoselectivities.

Graphical abstract: Carbonylative cycloaddition between two different alkenes enabled by reactive directing groups: expedited construction of bridged polycyclic skeletons

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Article information

DOI
https://doi.org/10.1039/D0CC05362G
Article type
Communication
Submitted
06 Aug 2020
Accepted
04 Sep 2020
First published
05 Sep 2020

Chem. Commun., 2020,56, 12198-12201

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Carbonylative cycloaddition between two different alkenes enabled by reactive directing groups: expedited construction of bridged polycyclic skeletons

B. Gao, S. Zou, G. Yang, Y. Ding and H. Huang, Chem. Commun., 2020, 56, 12198 DOI: 10.1039/D0CC05362G

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