A chiral sensor for recognition of varied amines based on 19F NMR signals of newly designed rhodium complexes

Wei Wang; Xiaohan Xia; Guangling Bian; Ling Song

doi:10.1039/C9CC01942A

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A chiral sensor for recognition of varied amines based on ¹⁹F NMR signals of newly designed rhodium complexes†

Wei Wang,‡^ab Xiaohan Xia,‡^a Guangling Bian

*^ab and Ling Song

*^ab

Author affiliations

* Corresponding authors

^a The Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: glb@fjirsm.ac.cn, songling@fjirsm.ac.cn

^b University of Chinese Academy of Sciences, Beijing, P. R. China

Abstract

A novel chiral octahedral rhodium complex containing fluorine has been developed to be an excellent chiral sensor for a variety of amines including diamines, monoamines, amino alcohols and amino acids, showing well distinguishable ¹⁹F NMR signals and an accurate measurement of enantiomeric determination.

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Article information

DOI: https://doi.org/10.1039/C9CC01942A
Article type: Communication
Submitted: 10 Mar 2019
Accepted: 30 Apr 2019
First published: 30 Apr 2019

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Chem. Commun., 2019,55, 6098-6101

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A chiral sensor for recognition of varied amines based on ¹⁹F NMR signals of newly designed rhodium complexes

W. Wang, X. Xia, G. Bian and L. Song, Chem. Commun., 2019, 55, 6098 DOI: 10.1039/C9CC01942A

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