The salen-Co(III) motif was inserted into imidazolium-functionalized multivariate cationic zirconium metal–organic frameworks (MOFs). The salen-Co(III), as a Lewis acid site, and the Br− of imidazolium, as a nucleophile, are synergistically catalytic for the enhanced cycloaddition reaction of carbon dioxide with epoxides.
T. Liu, J. Liang, R. Xu, Y. Huang and R. Cao, Chem. Commun., 2019, 55, 4063 DOI: 10.1039/C8CC10268F
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