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Electrostatic interactions between charged dielectric particles in an electrolyte solution: constant potential boundary conditions

Abstract

The problem of electrostatic interactions between colloidal particles in an electrolyte solution has been solved within the Debye - Hückel approximation using the boundary condition of constant potential. The model has been validated in two independent ways - by considering the limiting cases obtained from DLVO theory and comparison with available experimental data. The presented methodology provides the final part to a complete theory of pairwise electrostatic interactions be- tween spherical colloidal particles; one that embraces all possible chemical scenarios within the boundary conditions of constant potential and constant charge.

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Publication details

The article was accepted on 06 Jun 2018 and first published on 08 Jun 2018


Article type: Paper
DOI: 10.1039/C8SM01068D
Citation: Soft Matter, 2018, Accepted Manuscript
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    Electrostatic interactions between charged dielectric particles in an electrolyte solution: constant potential boundary conditions

    I. N. Derbenev, A. Filippov, A. J. Stace and E. Besley, Soft Matter, 2018, Accepted Manuscript , DOI: 10.1039/C8SM01068D

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