Issue 32, 2018, Issue in Progress

Block copolymer compatibilization driven frustrated crystallization in electrospun nanofibers of polystyrene/poly(ethylene oxide) blends

Abstract

The confined crystallization behaviour of poly(ethylene oxide) (PEO) has been studied in electrospun nanofibers of the phase-separated blends of polystyrene (PS) and PEO compatibilized with polystyrene-block-poly(ethylene oxide) (PS-b-PEO) block copolymer. The PS was present as the majority component such that the electrospun nanofibers consisted of PEO domains dispersed in the PS matrix. The phase separation in the blend occurred under the radial constraint of the nanofibers which led to the formation of small-sized fibrillar PEO domains. The use of block copolymer compatibilizer resulted in a noticeable decrease in the PEO domain size in the as-spun nanofibers. Moreover, the decrease in the domain size and domain connectivity was more substantial in the thermally annealed blend nanofibers due to the suppression of the domain coalescence mechanism resulting from the localization of the PS-b-PEO block copolymer at the interface. Consequently, the fraction of PEO domains crystallizing via homogeneous nucleation increased in the compatibilized blend nanofibers due to the presence of higher number of heterogeneity free PEO domains and disruption in their spatial connectivity. Interestingly, in the compatibilized blend nanofibers consisting of low molecular weight PEO, additional crystallization event attributed to surface nucleation was observed. The surface nucleation, plausibly, resulted from the formation of wet-brush structures where the PEO homopolymers homogeneously wet the PEO blocks present at the interface. In such a scenario, the PEO crystallization occurred via surface nucleation at the domain interface. The surface nucleated crystallization was absent in the compatibilized blend nanofibers composed of high molecular weight PEO presumably due to the formation of morphology with dry-brush structures.

Graphical abstract: Block copolymer compatibilization driven frustrated crystallization in electrospun nanofibers of polystyrene/poly(ethylene oxide) blends

Supplementary files

Article information

Article type
Paper
Submitted
19 Mar 2018
Accepted
08 May 2018
First published
16 May 2018
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2018,8, 17989-18007

Block copolymer compatibilization driven frustrated crystallization in electrospun nanofibers of polystyrene/poly(ethylene oxide) blends

P. Samanta, R. Srivastava and B. Nandan, RSC Adv., 2018, 8, 17989 DOI: 10.1039/C8RA02391C

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements