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Metal-free deoxygenative sulfonylation of quinoline N-oxides with sodium sulfinates via a dual radical coupling process

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Abstract

The first example of a metal- and reductant-free deoxygenative sulfonylation of quinoline N-oxides with sodium sulfinates via a dual radical coupling process is reported. In this reaction, sodium sulfinates play dual roles of a sulfonylation reagent and activating agent. This procedure is expected to complement the current methods for the radical reaction of quinoline N-oxides.

Graphical abstract: Metal-free deoxygenative sulfonylation of quinoline N-oxides with sodium sulfinates via a dual radical coupling process

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Publication details

The article was received on 03 Jul 2018, accepted on 27 Jul 2018 and first published on 07 Aug 2018


Article type: Research Article
DOI: 10.1039/C8QO00661J
Citation: Org. Chem. Front., 2018, Advance Article
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    Metal-free deoxygenative sulfonylation of quinoline N-oxides with sodium sulfinates via a dual radical coupling process

    L. Xie, S. Peng, F. Liu, G. Chen, W. Xia, X. Yu, W. Li, Z. Cao and W. He, Org. Chem. Front., 2018, Advance Article , DOI: 10.1039/C8QO00661J

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