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Palladium-catalyzed chemoselective anaerobic oxidation of N-heterocycle-containing alcohols

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Abstract

The palladium-catalyzed anaerobic oxidation for N-heterocycle-containing alcohols has been developed with chloroarenes as oxidants. In this process, primary and secondary alcohols were selectively oxidized even in the presence of cyclic amines as well as heteroarenes, and primary, secondary, and tertiary amino groups were found to be well tolerated. Moreover, a gram-scale chemoselective oxidation was achieved in addition to a double oxidation of a diamino diol.

Graphical abstract: Palladium-catalyzed chemoselective anaerobic oxidation of N-heterocycle-containing alcohols

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Publication details

The article was received on 26 Apr 2018, accepted on 28 Jun 2018 and first published on 29 Jun 2018


Article type: Research Article
DOI: 10.1039/C8QO00421H
Citation: Org. Chem. Front., 2018, Advance Article
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    Palladium-catalyzed chemoselective anaerobic oxidation of N-heterocycle-containing alcohols

    M. Kuriyama, S. Nakashima, T. Miyagi, K. Sato, K. Yamamoto and O. Onomura, Org. Chem. Front., 2018, Advance Article , DOI: 10.1039/C8QO00421H

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