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Issue 9, 2018
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Photoredox-catalyzed cascade annulation of methyl(2-(phenylethynyl)phenyl)sulfanes and methyl(2-(phenylethynyl)phenyl)selanes with sulfonyl chlorides: synthesis of benzothiophenes and benzoselenophenes

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Abstract

A photoredox-catalyzed cascade annulation of methyl(2-(phenylethynyl)phenyl)sulfanes and methyl(2-(phenylethynyl)phenyl)selanes with sulfonyl chlorides was developed. A variety of benzothiophenes and benzoselenophenes were obtained in moderate to good yields at ambient temperature.

Graphical abstract: Photoredox-catalyzed cascade annulation of methyl(2-(phenylethynyl)phenyl)sulfanes and methyl(2-(phenylethynyl)phenyl)selanes with sulfonyl chlorides: synthesis of benzothiophenes and benzoselenophenes

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Publication details

The article was received on 07 Feb 2018, accepted on 08 Mar 2018 and first published on 09 Mar 2018


Article type: Research Article
DOI: 10.1039/C8QO00147B
Citation: Org. Chem. Front., 2018,5, 1483-1487
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    Photoredox-catalyzed cascade annulation of methyl(2-(phenylethynyl)phenyl)sulfanes and methyl(2-(phenylethynyl)phenyl)selanes with sulfonyl chlorides: synthesis of benzothiophenes and benzoselenophenes

    J. Yan, J. Xu, Y. Zhou, J. Chen and Q. Song, Org. Chem. Front., 2018, 5, 1483
    DOI: 10.1039/C8QO00147B

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