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Imaging large amplitude out-of-plane motion in photoexcited pentafluorobenzene using time-resolved photoelectron spectroscopy: a computational study

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Abstract

Excited-state dynamics of pentafluorobenzene is studied in detail for a quartic vibronic coupling model including the six b1 vibrational modes of the molecule and the two lowest excited electronic states. The study analyzes the influence of the large-amplitude out-of-plane vibrational motion on the electronic dynamics and extends to the simulation of the emerging time-resolved photoelectron spectra. The mapping of coherent non-separable electron-nuclear motion into oscillatory photoelectron signals is discussed.

Graphical abstract: Imaging large amplitude out-of-plane motion in photoexcited pentafluorobenzene using time-resolved photoelectron spectroscopy: a computational study

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Publication details

The article was received on 31 Jan 2018, accepted on 29 Jun 2018 and first published on 04 Jul 2018


Article type: Paper
DOI: 10.1039/C8PP00051D
Citation: Photochem. Photobiol. Sci., 2018, Advance Article
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    Imaging large amplitude out-of-plane motion in photoexcited pentafluorobenzene using time-resolved photoelectron spectroscopy: a computational study

    M. Sala and D. Egorova, Photochem. Photobiol. Sci., 2018, Advance Article , DOI: 10.1039/C8PP00051D

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