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Molecular iodine-mediated synthesis of thiocarbamates from thiols, isocyanides and water under metal-free conditions

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Abstract

A simple and practical molecular iodine-mediated method for the efficient construction of thiocarbamates from isocyanides, thiols and water under metal-free and mild conditions has been developed. A variety of thiocarbamates were easily synthesized through this methodology, which has the advantages of simple operation, eco-friendly conditions, good functional group tolerance, and readily accessible raw materials.

Graphical abstract: Molecular iodine-mediated synthesis of thiocarbamates from thiols, isocyanides and water under metal-free conditions

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Publication details

The article was received on 28 Jul 2018, accepted on 04 Sep 2018 and first published on 14 Sep 2018


Article type: Paper
DOI: 10.1039/C8OB01820K
Citation: Org. Biomol. Chem., 2018, Advance Article
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    Molecular iodine-mediated synthesis of thiocarbamates from thiols, isocyanides and water under metal-free conditions

    W. Bao, C. Wu, J. Wang, W. Xia, P. Chen, Z. Tang, X. Xu and W. He, Org. Biomol. Chem., 2018, Advance Article , DOI: 10.1039/C8OB01820K

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