Jump to main content
Jump to site search


Synthesis of 2,2-difluoro-homoallylic alcohols via ring-opening of gem-difluorocyclopropane and aerobic oxidation by photo-irradiation in the presence of an organic pigment

Author affiliations

Abstract

We found that aerobic oxidation took place after the visible light-mediated ring-opening reaction of gem-difluorocyclopropane in the presence of an organic dye and amine to furnish 2,2-difluoro-homoallylic alcohols in good yields.

Graphical abstract: Synthesis of 2,2-difluoro-homoallylic alcohols via ring-opening of gem-difluorocyclopropane and aerobic oxidation by photo-irradiation in the presence of an organic pigment

Back to tab navigation

Supplementary files

Publication details

The article was received on 20 Jul 2018, accepted on 06 Aug 2018 and first published on 06 Aug 2018


Article type: Paper
DOI: 10.1039/C8OB01740A
Citation: Org. Biomol. Chem., 2018, Advance Article
  •   Request permissions

    Synthesis of 2,2-difluoro-homoallylic alcohols via ring-opening of gem-difluorocyclopropane and aerobic oxidation by photo-irradiation in the presence of an organic pigment

    H. Takenaka, Y. Masuhara, K. Narita, T. Nokami and T. Itoh, Org. Biomol. Chem., 2018, Advance Article , DOI: 10.1039/C8OB01740A

Search articles by author

Spotlight

Advertisements