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Nickel-catalyzed direct C–H bond sulfenylation of acylhydrazines

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Abstract

A Ni-catalyzed direct C–H bond sulfenylation of acylhydrazines was developed. The reaction used N-(pyridinyl)hydrazine as the bidentate-directing group, which can be smoothly removed through reductive N–N cleavage. This system can bear various important functional groups, providing an efficient route for the preparation of diverse diaryl sulfides.

Graphical abstract: Nickel-catalyzed direct C–H bond sulfenylation of acylhydrazines

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Publication details

The article was received on 22 Jun 2018, accepted on 01 Aug 2018 and first published on 01 Aug 2018


Article type: Paper
DOI: 10.1039/C8OB01481G
Citation: Org. Biomol. Chem., 2018, Advance Article
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    Nickel-catalyzed direct C–H bond sulfenylation of acylhydrazines

    J. Li, Y. Yu, J. Weng and G. Lu, Org. Biomol. Chem., 2018, Advance Article , DOI: 10.1039/C8OB01481G

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